CeF₃ (Cerium Trifluoride ) Crystal

CeF₃ (Cerium Trifluoride ) Crystals are a high-performance magneto-optic crystal product with outstanding overall characteristics.

Keywords:

Scintillation Crystals

Product Category:

  • Product Introduction
  • Key advantages
  • Application areas
  • Product Features
    • Commodity name: CeF₃ (Cerium Trifluoride ) Crystal

    CeF₃ (Cerium Trifluoride ) Crystals are a high-performance magneto-optic crystal product with outstanding overall characteristics.

    Product Introduction

    CeF₃ (Cerium Trifluoride ) Crystals are a high-performance magneto-optic crystal product with outstanding overall characteristics. Currently, the most commonly used magneto-optic crystal is terbium gallium garnet (TGG), which plays a critical role in applications such as magneto-optic isolators, modulators, phase shifters, switches, and circulators. However, TGG’s limited transparency in the ultraviolet range (<400 nm) severely restricts its use in UV-related applications. In contrast, CeF₃ crystals belong to the hexagonal crystal system and boast an exceptionally wide transmission window, with a cutoff wavelength below 300 nm—making them a vital material for UV-range magneto-optic devices. Moreover, CeF₃ crystals do not suffer from the "core-shell" issue often encountered in other materials, resulting in high raw material utilization efficiency. CeF₃ crystals also offer several advantageous properties, including high density, excellent thermal stability, superior detection efficiency, and rapid response times. These attributes make them ideally suited as detector materials for high-energy physics experimental setups. As a result, CeF₃ finds extensive applications in fields such as Faraday isolators, X-ray detectors, beta-ray detectors, and gamma-ray detectors. Additionally, CeF₃ is recognized as a scintillating crystal—a promising new class of inorganic scintillators widely employed in medical imaging and high-energy physics. It stands out for its high density, short decay time, and remarkable radiation hardness, further enhancing its versatility and performance in cutting-edge scientific and medical technologies.

    Materials like CeF₃ represent a class of outstanding, cutting-edge magneto-optic materials that hold the potential to fundamentally change the current reliance on foreign suppliers for large-scale magneto-optic crystal components. This breakthrough will strongly support the development of China’s high-power all-solid-state lasers and the optical communication industry.

     

    Key Advantages

    - Excellent temperature stability 
    - High density 
    - Fast decay time 
    - Non-dissolving 
    - High light yield 
    - Superior radiation hardness

     

    Application Areas

    - X-Ray 
    - Faraday isolator 
    -Gamma-ray detection 
    -β-ray detection 
    - High-energy and nuclear physics
    -PET

     

    Product Features

    Material Properties

    Materials

    CeF₃

    Density

    6.16 g/cm³

    Melting Point

    1443°C

    Refractive Index

    1.62 @ 400 nm

    Radiation Length

    1.68 cm

    Emission Peak

    340 nm (slow); 300 nm (fast)

    Attenuation Constant

    30 ns (slow); 8 ns (fast)

    Light Output 

    8.6 [NaI(Tl) = 100%]

    Wavelength (maximum emission)

    286 nm, 300 nm, 340 nm

    Wavelength Range 

    280-700 nm

    Decay Time

    5-30 ns

    Luminous Intensity 

    7,000-12,000 photons/MeV

    Radiation Length

    1.68 cm

    Absorption Length

    3.5 (cm) -1

    Light Output 

    340-470 photons/MeV

    Thermal Neutron Cross Section

    0.65 Target

    Product Processing Indicators

    Effective Aperture

    >90%

    Diameter Tolerance

    +0/-0.05 mm

    Length Tolerance

    ±0.1 mm

    Chamfer

    ≤0.2 × 45°

    Surface Quality

    10-5 S-D

    Flatness

    ≤λ/6 @ 632.8 nm

    Wavefront Distortion

    ≤λ/6 @ 632.8 nm

    Parallelism

    <20"

    Perpendicularity

    ≤15′

    Chipped Edge

    <0.1 mm

    Coating

    Customized to Customer Specifications

  • - High magneto-optic constant (35 Rad T⁻¹m⁻¹).
    - Low light loss (<0.1% / cm)
    - High thermal conductivity (4 W m⁻¹K⁻¹).
    - High laser damage threshold (> 1 GW/cm²).
    - Absorption coefficient (<0.1%/cm)

  • - Ion-Irradiated Magneto-Optic Waveguide
    - Faraday Rotator
    - Fiber optic isolator
    - Free-space isolator
    - Magneto-optic switches and magneto-optic modulators

  • Material Properties
    Molecular formula Tb3Ga5O12
    Crystal structure Cubic crystal system
    Production method Tiraf Method
    Density 7.13g/cm3
    Mohs Hardness 8Mohs
    Unit cell parameters a = 12.355 Å
    Transmittance range 400 nm to 1100 nm
    Wiedemann constant (rad/T/m) 40 at 1064nm
    Refractive index 1.954 @ 1064 nm
    Melting point 1725°C
    Product Processing Metrics
    Directional

    [111] ±15′

    Extinction Ratio ≥30dB
    Effective Aperture >90%
    Maximum size <∮100mm
    Diameter Tolerance +0 / -0.05 mm
    Length Tolerance ±0.2 mm
    Protective Chamfer ≤0.2 × 45°
    Surface finish 10-5 S-D
    Flatness ≤λ/8 @ 632.8 nm
    Analyzing wavefront distortion ≤λ/8 @ 632.8 nm
    Parallelism <20"
    Verticality ≤15′
    Chipped edge <0.1 mm
    Coating AR:R < 0.2% @ 1064 nm

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